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Bio-based vitrimer-like polyurethane based on dynamic imine bond with high-strength, reprocessability, rapid-degradability and antibacterial ability
Bio-based polyurethane Vitrimer-like Imine bond Rapidly-degradable Antibacterial property
2023/12/8
Synthesis of vitrimer with dynamic?covalent bond?is a surprising solution to overcome the inherent limitations of traditional?thermosets. A bio-based vitrimer-like?polyurethane?formed by?castor oil,?v...
Rapid self-healing and self-adhesive chitosan-based hydrogels by host-guest interaction and dynamic covalent bond as flexible sensor
Conductive hydrogel Chitosan Poly(vinyl alcohol) Host-guest interactions Self-healing Self-adhesiveness Flexible strain sensor
2023/12/8
A sensor used to monitor tissue deformation requires good flexibility, stretchability, self-adhesion, cyto-compatibility, and?antibacterial property. Here, we prepared hydrogel sensor based on?O-carbo...
Epoxy vitrimer based on borate ester bond for green degradation, closed-loop recycling, and ready reprocessing
Green degradation Thermoset Dynamic covalent bond Recyclable
2023/12/1
The three-dimensional network of traditional epoxy resin endows it with suitable properties, but it also presents challenges in reprocessing and recycling. Recent years have witnessed the development ...
Exploring the effects of bound rubber phase on the physical properties of nano-silica composites with a vitrimer-like bond exchangeable matrix
DYNAMIC COVALENT CHEMISTRY CROSS-LINK DENSITY MECHANICAL-PROPERTIES POLYMER NANOCOMPOSITES
2023/11/30
We demonstrate the preparation and unique properties of composite vitrimer-like materials containing silica nanoparticles (SNPs). The matrix is composed of polyacrylate-based polymers crosslinked via ...
A Novel Polyvinyl Alcohol-Based Hydrogel with Ultra-Fast Self-Healing Ability and Excellent Stretchability Based on Multi Dynamic Covalent Bond Cross-Linking
dynamic covalent bonds hydrogels self-healing strain sensors
2023/11/30
A novel self-healing poly(vinyl alcohol) (PVA)-based hydrogel is developed by cross-linking PVA chains through multi dynamic covalent bonds by use of a small cross-linker composed by 4-formylphenylbor...
Dissecting Proton Delocalization in an Enzyme’s Hydrogen Bond Network with Unnatural Amino Acids
Dissecting Proton Delocalization Enzyme’s Hydrogen Bond Network Unnatural Amino Acids
2016/5/25
Extended hydrogen bond networks are a common structural motif of enzymes. A recent analysis proposed quantum delocalization of protons as a feature present in the hydrogen bond network spanning a tria...
Quantum delocalization of protons in the hydrogen-bond network of an enzyme active site
ab initio path integral molecular dynamics enzyme hydrogen bonding nuclear quantum effects proton delocalization
2016/5/25
Enzymes use protein architectures to create highly specialized structural motifs that can greatly enhance the rates of complex chemical transformations. Here, we use experiments, combined with ab init...
Putative Hydrogen Bond to Tyrosine M208 in Photosynthetic Reaction Centers from Rhodobacter capsulatus Significantly Slows Primary Charge Separation
Coagulation Nano TiO2 Nano Al2O3 Breakage Fractal dimension
2016/5/25
Slow, ～50 ps, P* → P(+)HA(-) electron transfer is observed in Rhodobacter capsulatus reaction centers (RCs) bearing the native Tyr residue at M208 and the single amino acid change of isoleucine at M20...
A conserved water-mediated hydrogen bond network defines bosutinib’s kinase selectivity
Humans Water Quinolines Nitriles Aniline Compounds src-Family Kinases Amino Acid Substitution Conserved Sequence Substrate Specificity Hydrogen Bonding
2016/5/25
Kinase inhibitors are important cancer drugs, but they tend to display limited target specificity, and their target profiles are often challenging to rationalize in terms of molecular mechanism. Here ...
Quantitative Dissection of Hydrogen Bond-Mediated Proton Transfer in the Ketosteroid Isomerase Active Site
active site environment computational modeling enzyme catalysis protein electrostatics protein semisynthesis
2016/5/25
Hydrogen bond networks are key elements of protein structure and function but have been challenging to study within the complex protein environment. We have carried out in-depth interrogations of the ...
Municipal Bond Boom in Hungary: Focusing on the Analysis of Local Financial Management
Borrowing Financial management Local governments Municipal bonds
2016/1/27
The drastic increase in volume of local government debt in Hungary started in 2006. My hypothesis assumes that a supposable improvement in local municipal financial management might resulted in the sp...
Enhancing Estimation for Interest Rate Diffusion Models with Bond Prices
Interest Rate Models Affine Term Structure Bond Prices Market Price of Risk Combined Estimation Parameter Estimation
2016/1/26
We consider improving estimating parameters of diffusion processes for interest rates by incorporating information in bond prices. This is designed to improve the estimation of the drift parameters, w...
Enhancing Estimation for Interest Rate Diffusion Models with Bond Prices
Interest Rate Models Affine Term Structure Bond Prices Market Price of Risk Combined Estimation Parameter Estimation
2016/1/20
We consider improving estimating parameters of diffusion processes for interest rates by incorporating information in bond prices. This is designed to improve the estimation of the drift parameters, w...
Casein Phosphopeptide-Amorphous Calcium Phosphate and Shear Bond Strength of Adhesives to Primary Teeth Enamel
CPP-ACP Bond Strength (BS) Adhesive
2015/10/20
Background: CPP-ACP (Phosphopeptide-Amorphous Calcium Phosphate) has an important role in caries prevention in pediatric patients. This study was done, because of the great use of CPP-ACP and the need...
Discussion of "The Cross Section and Time Series of Stock and Bond Returns" by Koijen, Lustig & Van Nieuwerburgh
Cross Section Stock and Bond Returns
2015/7/23
A￠ ne model in which:
ñ 3 priced factors explain the cross section of bond and stock returns:
level, CP, DP
ñ 2 factors explain the time variation in bond and stock returns:
CP, DP